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She has a light amber coat, red and brilliant yellow mane and tail, and a cutie mark of a red and yellow shimmering sun.
Her name follows the same pattern as Twilight Sparkle, Starlight Glimmer, and Starbeam Twinkle.
Twilight refuses to give the crown up, stating that her being stuck in the human world would be worth stopping Sunset.
As Twilight's friends commend her bravery and sacrifice, Sunset snaps and attacks her.
Despite Twilight and her friends' efforts, Sunset succeeds in getting the crown and puts it on, and a dark magic aura transforms her into a demon.
With her newfound powers, Sunset transforms Snips and Snails into similar-looking minions and brainwashes the other students at the school.
She admits to not knowing anything about friendship, to which Twilight says her friends can teach her.
Sunset, Snips, and Snails are later tasked by Vice Principal Luna with rebuilding the part of school they had destroyed during their attack.
When the Rainbooms lash out at each other during the final round of the Battle of the Bands, Sunset realizes what the Dazzlings' true intentions are and is able to stop the petty arguing.
She even accepts partial blame due to her lack of knowledge on friendship.
When the Dazzlings overpower the Rainbooms during the film's climax, Sunset Shimmer steps up and sings on the band's behalf.
Following her appearance in Equestria Girls, she has since appeared in other films, animated shorts, software, film novelizations and chapter books, and several IDW comics.
Sunset Shimmer resembles the G3 Earth pony Sunshimmer in pony design and name.